Biomimetic synthesis and structural revision of (+/-)-tridachiahydropyrone.
نویسندگان
چکیده
A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data matched that of the isolated natural product, supporting a revised structure of this complex metabolite.
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عنوان ژورنال:
- Organic letters
دوره 10 18 شماره
صفحات -
تاریخ انتشار 2008